|
|
S-adenosyl-L-methionine + R-2-hydroxy-3-methylpentanoyl-[acp] + ATP + L-valine <=> R-2-hydroxy-3-methylpentanoyl-methylvalyl-[acp] + AMP + diphosphate + H+ + S-adenosyl-L-homocysteine
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16638
|
|
|
|
R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-[acp] + ATP + L-leucine <=> R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-Leu-[acp] + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16644
|
|
|
|
S-adenosyl-L-methionine + R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanyl-[acp] + ATP + L-phenylalanine <=> R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanyl-[acp] + AMP + diphosphate + H+ + S-adenosyl-L-homocysteine
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16640
|
|
|
|
R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanyl-[acp] + ATP + L-proline <=> R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanine-prolyl-[acp] + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16641
|
|
|
|
2-hydroxyisocaproate + [acyl-carrier_protein] + ATP <=> R-2-hydroxy-3-methylpentanoyl-[acp] + AMP + diphosphate
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16636
|
|
|
|
R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanine-prolyl-[acp] + ATP + L-allo-isoleucine <=> R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanine-proline-allo-isoleucyl-[acp] + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16642
|
|
|
|
S-adenosyl-L-methionine + R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanine-methylphenylalanine-proline-allo-isoleucyl-[acp] + ATP + L-valine <=> R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-[acp] + AMP + diphosphate + H+ + S-adenosyl-L-homocysteine
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16643
|
|
|
|
R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-Leu-MeVal-[acp] <=> aureobasidin_A + [acyl-carrier_protein]
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16646
|
|
|
|
S-adenosyl-L-methionine + R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-Leu-[acp] + ATP + L-valine + NADPH + O2 <=> R-Hmp-MeVal-Phe-MePhe-Pro-alle-MeVal-Leu-MeVal-[acp] + AMP + diphosphate + S-adenosyl-L-homocysteine + NADP+ + H2O + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16645
|
|
|
|
R-2-hydroxy-3-methylpentanoyl-methylvalyl-[acp] + ATP + L-phenylalanine <=> R-2-hydroxy-3-methylpentanoate-methylvaline-phenylalanyl-[acp] + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-16639
|
|
